基于4,4’-磺酰基二苯甲酸配体构筑的稀土有机框架及荧光传感性能研究
PDF下载 (243)曾 成,刘 楠,吴 贞,吕 沛,郑慧玲,许 伟.基于4,4’-磺酰基二苯甲酸配体构筑的稀土有机框架及荧光传感性能研究[J].宁波大学学报(理工版),2023,36(6):70-76.DOI:10.20098/j.cnki.1001-5132.2023.0508
ZENG Cheng,LIU Nan,WU Zhen,L? Pei,ZHENG Huiling,XU Wei.Rare-earth organic framework based on 4,4’-sulfonyl group dibenzoic acid ligand and its fluorescence sensing properties[J].Journal of Ningbo University(Natural Science & Engineering Edition),2023,36(6):70-76.DOI:10.20098/j.cnki.1001-5132.2023.0508
| Title: | Rare-earth organic framework based on 4,4’-sulfonyl group dibenzoic acid ligand and its fluorescence sensing properties |
| 作者: | 曾 成, 刘 楠, 吴 贞, 吕 沛, 郑慧玲, 许 伟 |
| Author(s): | ZENG Cheng, LIU Nan, WU Zhen, L? Pei, ZHENG Huiling, XU Wei |
| 关键词: | 金属有机骨架材料; 4,4’-磺酰基二苯甲酸; 荧光传感; 维生素B4; 阿奇霉素; 4,4’-sulfoyldibenzoic acid |
| Keywords: | metal-organic frameworks; fluorescence sensing; vitamin B4; azithromycin |
| 分类号: | O652.3 |
| DOI: | 10.20098/j.cnki.1001-5132.2023.0508 |
| 文献标识码: | A |
| 摘要: | 在溶剂热条件下, 以4,4’-磺酰基二苯甲酸(H2SDBA)为配体与硝酸铕构建出具有荧光性质的稀土有机框架[Eu2(SDBA)3(H2O)4]NMP (NMP=N-甲基吡咯烷酮), 并对其进行粉末X射线衍射、荧光光谱、紫外吸收光谱等手段表征. X射线单晶衍射分析结果显示该材料具有三维结构. Eu-MOFs具有良好的荧光性能, 能够在水中同时实现对维生素B4和阿奇霉素的高灵敏及高选择的荧光淬灭检测. |
| Abstract: | A new metal-organic framework (MOF), [Eu2(SDBA)3(H2O)4]NMP (H2SDBA=4,4’-sulfonyldibenzoic acid; NMP=N-methylpyrrolidone), has been successfully synthesized under solvothermal condition. The complex is characterized by PXRD, PL and UV-Vis. The X-ray single crystal diffraction analysis reveals that the compound has a three-dimensional structure. It has some desired fluorescence properties and can achieve highly sensitive and highly selective fluorescence quenching detection with vitamin B4 and azithromycin in aqueous. |
| 参考文献 /References: | [1] [1] Yu M M, Li H X, Xie J Y, et al. A descriptive and comparative analysis on the adsorption of PPCPs by molecularly imprinted polymers[J]. Talanta, 2022, 236: 122875. [2] [2] Li J X, Guan Q L, You Z X, et al. Achieving multifunctional detection of Th4+ and UO22+ in the post-synthetically modified metal-organic framework and application of functional MOF membrane[J]. Advanced Materials Technologies, 2021, 6(7):2001184. [3] [3] Yu H H, Chi J Q, Su Z M, et al. A water-stable terbium metal-organic framework with functionalized ligands for the detection of Fe3+ and Cr2O72– ions in water and picric acid in seawater[J]. CrystEngComm, 2020, 22(21):3638- 3643. [4] [4] Guo F, Su C H, Fan Y H, et al. Assembly of two self-interpenetrating metal-organic frameworks based on a trigonal ligand: Syntheses, crystal structures, and properties[J]. Inorganic Chemistry, 2020, 59(10):7135- 7142. [5] [5] Samanta P, Let S, Mandal W, et al. Luminescent metal- organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants[J]. Inorganic Chemistry Frontiers, 2020, 7(9):1801-1821. [6] [6] 王凯民, 石明凤, 李立凤, 等. 混合配体构筑的水相高稳定Zn(Ⅱ)金属有机框架铁离子荧光探针[J]. 中山大学学报(自然科学版)(中英文), 2023, 62(1):142-148. [7] [7] Yin H Q, Yin X B. Metal-organic frameworks with multiple luminescence emissions: Designs and applications [J]. Accounts of Chemical Research, 2020, 53(2):485- 495. [8] [8] Melfi M T, Nardiello D, Cicco N, et al. Simultaneous determination of water- and fat-soluble vitamins, lycopene and beta-carotene in tomato samples and pharmaceutical formulations: Double injection single run by reverse-phase liquid chromatography with UV detection [J]. Journal of Food Composition and Analysis, 2018, 70: 9-17. [9] [9] Han R W, Zheng N, Yu Z N, et al. Simultaneous determination of 38 veterinary antibiotic residues in raw milk by UPLC-MS/MS[J]. Food Chemistry, 2015, 181: 119-126. [10] [10] Emrani A S, Danesh N M, Lavaee P, et al. Colorimetric and fluorescence quenching aptasensors for detection of streptomycin inblood serum and milk based on double-stranded DNA and gold nanoparticles[J]. Food Chemistry, 2016, 190:115-121. [11] [11] Huang L, Tian S L, Zhao W H, et al. Electrochemical vitamin sensors: A critical review[J]. Talanta, 2021, 222: 121645. [12] [12] Losoya-Leal A, Estevez M C, Martínez-Chapa S O, et al. Design of a surface plasmon resonance immunoassay for therapeutic drug monitoring of amikacin[J].Talanta, 2015, 141:253-258. [13] [13] Wu S Y, Min H, Shi W, et al. Multicenter metal-organic framework-based ratiometric fluorescent sensors[J]. Advanced Materials (Deerfield Beach, Fla), 2020, 32(3): e1805871. [14] [14] 朱圣加, 陈飞, 张柔, 等. CdI2-phen/bpy溶剂热体系中Cd(Ⅱ)配合物的合成、晶体结构及荧光传感性能研究[J]. 化学试剂, 2022, 44(6):846-849. [15] [15] Shi Y X, Wang Z B, Meng T, et al. Red phosphorescent carbon quantum dot organic framework-based electro- luminescent light-emitting diodes exceeding 5% external quantum efficiency[J]. , 2021, 143(45):18941-18951. [16] [16] Fu Y, Zhang R, Lv P, et al. Eu-based metal-organic framework as a multi-responsive fluorescent sensor for efficient detecting Cr2O72? and tetracycline hydrochloride [J]. Journal of Solid State Chemistry, 2022, 306:122724. [17] [17] Wang Q, Li X C, Yang K, et al. Carbon dots and Eu3+ hybrid-based ratiometric fluorescent probe for oxytetracycline detection[J]. , 2022, 61(17):5825-5832. [18] [18] Sun T C, Wang P, Fan R Q, et al. Functional microscale single-phase white emission lanthanide MOF for tunable fluorescent sensing and water quality monitoring[J]. Journal of Materials Chemistry C, 2019, 7(12):3598- 3606. [19] [19] Wang C Y, Wang C C, Zhang X W, et al. A new Eu-MOF for ratiometrically fluorescent detection toward quinolone antibiotics and selective detection toward tetracycline antibiotics[J]. Chinese Chemical Letters, 2022, 33(3):1353-1357. [20] [20] Wang X Q, Ma X H, Feng D D, et al. Four novel lanthanide(III) metal-organic frameworks: Tunable light emission and multiresponsive luminescence sensors for vitamin B6 and pesticides[J]. Crystal Growth & Design, 2021, 21(5):2889-2897. [21] [21] Liu J Q, Li X L, Han Y D, et al. Synergetic effect of tetraethylammonium bromide addition on the morphology evolution and enhanced photoluminescence of rare-earth metal-organic frameworks[J]. Inorganic Chemistry, 2020, 59(19):14318-14325. [22] [22] Yao S L, Xiong Y C, Tian X M, et al. A multifunctional benzothiadiazole-based fluorescence sensor for Al3+, Cr3+ and Fe3+[J]. CrystEngComm, 2021, 23(9):1898-1905. [23] [23] Chen M, Xu W M, Tian J Y J T, et al. A terbium(iii) lanthanide-organic framework as a platform for a recyclable multi-responsive luminescent sensor[J]. Journal of Materials Chemistry C, 2017, 5(8):2015-2021. |
| 备注/Memo: | 收稿日期:2023-05-10.宁波大学学报（理工版）网址:http://journallg.nbu.edu.cn/ 基金项目:福州大学能源与环境光催化国家重点实验室开放课题（SKLPEE-KF202207）;国家级大学生创新创业训练计划项目（202211646023）. 第一作者:曾成（1997－）,男,湖北孝感人,在读硕士研究生,主要研究方向:功能材料的合成及性质.E-mail:873137349@qq.com *通信作者:许伟（1981－）,男,浙江天台人,教授,主要研究方向:功能材料的合成及性质.E-mail:xuwei@nbu.edu.cn 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ |
