基于Sb3+离子掺杂Cs2NaYCl6双钙钛矿的改性研究
PDF下载 (67)林 洁,胡建旭,张约品.基于Sb3+离子掺杂Cs2NaYCl6双钙钛矿的改性研究[J].宁波大学学报(理工版),2026,39(1):58-68.DOI:10.20098/j.cnki.1001-5132.2025.0410
LIN Jie,HU Jianxu,ZHANG Yuepin.Modification research based on Sb3+ ion doping of Cs2NaYCl6 double perovskite[J].Journal of Ningbo University(Natural Science & Engineering Edition),2026,39(1):58-68.DOI:10.20098/j.cnki.1001-5132.2025.0410
| Title: | Modification research based on Sb3+ ion doping of Cs2NaYCl6 double perovskite |
| 作者: | 林 洁, 胡建旭, 张约品 |
| Author(s): | LIN Jie, HU Jianxu, ZHANG Yuepin |
| 关键词: | 双钙钛矿; 离子掺杂; 自陷激子; 能量转移 |
| Keywords: | double perovskite; ion doping; self-trapped exciton; energy transfer |
| 分类号: | O482.3 |
| DOI: | 10.20098/j.cnki.1001-5132.2025.0410 |
| 文献标识码: | A |
| 摘要: | 旨在克服无铅双钙钛矿材料在应用中面临的低发射效率和光谱调节困难两大障碍，探索其在下一代固态照明中的巨大潜力。通过水热法合成制备出Sb3+/Tb3+共掺杂的Cs2NaYCl6单晶，并运用多种表征手段对其进行深入分析。结果表明：在宿主中引入Sb3+离子可显著增强辐射复合自陷激子（Self-Trapped Exciton，STE），进而产生蓝色发射；而引入Tb3+离子后，光谱中出现源于Sb3+自陷激子到掺杂离子能量转移的可调双发射。所制备的新材料在荧光温度检测方面展现出潜在应用前景，有望拓展其在下一代固态照明等领域的应用。 |
| Abstract: | This study aims to overcome the two major obstacles of low emission efficiency and spectral tuning difficulties faced by lead-free bicarbonate materials in applications, and to explore their great potentials in the next-generation solid-state lighting. Sb3+/Tb3+ co-doped Cs2NaYCl6 single crystals were prepared by hydrothermal synthesis and analyzed in depth using a variety of characterization tools. The results show that the introduction of Sb3+ ions into the host significantly enhances the radiative composite self-trapped exciton, which in turn generates a large amount of blue emission, whereas the introduction of Tb3+ ions results in the emergence of spectra originating from the Sb3+ self-trapped exciton to doped ion energy transfer of tunable double emission. The prepared new material shows potential application prospect in fluorescence temperature detection, which is expected to expand its applications in more fields such as next-generation solid-state lighting |
| 参考文献 /References: | [1].WANG Y N, LIU J X, LIU Y J, et al. Recent advances in lead-free halide perovskites: from synthesis to applications[J]. Journal of materials chemistry C, 2024, 12(28):10267-10329. [2].YANG Q H, WEI H Q, LI G-H, et al. Recent developments of lead-free halide-perovskite Cs3Cu2X5 (X=Cl, Br, I): synthesis, modifications, and applications [J]. Materials today physics, 2023, 36:101143. [3].CHEN X, JIA M C, XU W, et al. Recent progress and challenges of bismuth-based halide perovskites for emerging optoelectronic applications[J]. Advanced optical materials, 2022, 11(3):2202153. [4].SUN J C, WU J, TONG X, et al. Organic/inorganic metal halide perovskite optoelectronic devices beyond solar cells[J]. Advanced science, 2018, 5(5):1700780. [5].INFANTE I, MANNA L. Are there good alternatives to lead halide perovskite nanocrystals?[J]. Nano letters, 2020, 21(1):6-9. [6].DE ANGELIS F. The prospect of lead-free perovskite photovoltaics[J]. ACS energy letters, 2021, 6(4):1586-1587. [7].JIN S L, YUAN H, PANG T, et al. Boosting STE and Nd3+ NIR luminescence in Cs2AgInCl6 double perovskite via Na+/Bi3+: induced local structure engineering[J]. Advanced functional materials, 2023, 33(50):2304577. [8].LI X, WANG D D, ZHONG Y, et al. Halide double perovskite nanocrystals doped with rare-earth ions for multifunctional applications[J]. Advanced science, 2023, 10(20):2207571. [9].LI H H, WANG Y K, LIAO L S. Near-infrared luminescent materials incorporating rare earth/transition metal ions: from materials to applications[J]. Advanced materials, 2024, 36(30):2403076. [10].KIRCHARTZ T. Photon management in perovskite solar cells[J]. The journal of physical chemistry letters, 2019, 10(19):5892-5896. [11].SUN H T, ZHOU J J, QIU J R. Recent advances in bismuth activated photonic materials[J]. Progress in materials science, 2014, 64:1-72. [12].LI Y, XU S, GAO Y F, et al. Thermochromic Cs2NaInCl6: Sb3+/Ln3+ (Ln=Er, Dy, Tb, Ho) phosphors for multi- functional applications[J]. Ceramics international, 2024, 50(8):13378-13387. [13].GUO X X, WEI J H, LUO J B, et al. All inorganic Sb3+-Ln3+-codoped Cs2NaYCl6 for highly efficient single-source white-light emission and ratiometric optical thermometer applications[J]. Advanced optical materials, 2023, 12(7):2301914. [14].WANG Y H, BAI S C, SUN J, et al. Highly efficient visible and near-infrared luminescence of Sb3+, Tm3+ co-doped Cs2NaYCl6 lead-free double perovskite and light emitting diodes[J]. Journal of alloys and compounds, 2023, 947:169602. [15].PAN Y W, ZHANG Y F, KANG W M, et al. Progress in the preparation and application of CsPbX3 perovskites[J]. Materials advances, 2022, 3(10):4053-4068. [16].ZHANG G Y, WANG D Y, LOU B B, et al. Efficient broadband near-infrared emission from lead-free halide double perovskite single crystal[J]. Angewandte chemie international edition, 2022, 61(33):e202207454. [17].ZHOU L, LIAO J F, KUANG D B. An overview for zero-dimensional broadband emissive metal-halide single crystals[J]. Advanced optical materials, 2021, 9(17): 2100544. [18].TAO H B, FANG Y Y, ZHANG Y P, et al. Dual-modal optical temperature sensing based on Sb3+/Mn2+ co-doped Cs2NaYCl6 double perovskites[J]. Ceramics international, 2024, 50(16):28877-28885. [19].QIAO J W, ZHAO J, LIU Q L, et al. Recent advances in solid-state LED phosphors with thermally stable luminescence[J]. Journal of rare earths, 2019, 37(6):565- 572. [20].ZHANG X G, HUANG Y M, GONG M L. Dual-emitting Ce3+, Tb3+ co-doped LaOBr phosphor: luminescence, energy transfer and ratiometric temperature sensing[J]. Chemical engineering journal, 2017, 307:291-299. [21].XUE J P, YU Z K, NOH H M, et al. Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln=Eu, Tb, Dy, Sm) phosphors[J]. Chemical engineering journal, 2021, 415:128977. [22].WANG Q, LIAO M, LIN Q M, et al. A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials[J]. Journal of alloys and compounds, 2021, 850:156744. [23].WANG X F, LIU Q, BU Y Y, et al. Optical temperature sensing of rare-earth ion doped phosphors[J]. RSC advances, 2015, 105:86219-86236. [24].LIAO J S, WANG M H, KONG L Y, et al. Dual-mode optical temperature sensing behavior of double- perovskite CaGdMgSbO6:Mn4+/Sm3+ phosphors[J]. Journal of luminescence, 2020, 226:117492. [25].ZHOU H T, GUO N, ZHU M M, et al. Photolumine- scence and ratiometric optical thermometry in Mn4+/Eu3+ dual-doped phosphor via site-favorable occupation[J]. Journal of luminescence, 2020, 224:117311. [26].LI L, TIAN G, DENG Y S, et al. Constructing ultra-sensitive dual-mode optical thermometers: utilizing FIR of Mn4+/Eu3+ and lifetime of Mn4+ based on double perovskite tellurite phosphor[J]. Optics express, 2020, 28(22):33747. [27].SONG Y Y, GUO N, LI J, et al. Photoluminescence and temperature sensing of lanthanide Eu3+ and transition metal Mn4+ dual-doped antimoniate phosphor through site-beneficial occupation[J]. Ceramics international, 2020, 46(14):22164-22170. [28].CHEN D Q, XU W, YUAN S, et al. Ln3+-sensitized Mn4+near-infrared upconverting luminescence and dual- modal temperature sensing[J]. Journal of materials chemistry C, 2017, 5(37):9619-9628. [29].SONG R X, XU S, LI Y, et al. Designing multi-mode optical thermometers via Sb3+/Er3+ co-doped Cs2NaInCl6 lead-free double perovskite microcrystals[J]. Journal of alloys and compounds, 2023, 961:171126. [30].SONG J, ZHAO W, ZHANG H, et al. Energy transfer and ratiometric temperature sensing based on the dual- emitting NaMgBO3:Ce3+, Mn2+ phosphor[J]. Journal of luminescence, 2021, 232:117858. [31].ZHANG X G, XU J G, GUO Z Y, et al. Luminescence and energy transfer of dual-emitting solid solution phosphors (Ca, Sr)10Li(PO4)7:Ce3+, Mn2+ for ratiometric temperature sensing[J]. Industrial & engineering chemistry research, 2017, 56(4):890-898. [32].XUE J P, YU Z K, NOH H M, et al. Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln=Eu, Tb, Dy, Sm) phosphors[J]. Chemical engineering journal, 2021, 415:128977. [33].JIANG Y C, TONG Y, CHEN S, et al. A three-mode self-referenced optical thermometry based on up-conversion luminescence of Ca2MgWO6:Er3+, Yb3+ phosphors[J]. Chemical engineering journal, 2021, 413: 127470. [34].XUE J P, SONG M J, NOH H M, et al. Achieving non- contact optical thermometer via inherently Eu2+/Eu3+- activated SrAl2Si2O8 phosphors prepared in air[J]. Journal of alloys and compounds, 2020, 843:155858. [35].LIU W G, WANG X J, ZHU Q, et al. Tb3+/Mn2+ singly/ doubly doped Sr3Ce(PO4)3 for multi-color luminescence, excellent thermal stability and high-performance optical thermometry[J]. Journal of alloys and compounds, 2020, 829:154563. [36].ZHU F, GAO Y, ZHAO C, et al. Achieving broadband NIR-I to NIR-Ⅱ emission in an all-inorganic halide double-perovskite Cs2NaYCl6:Cr3+ phosphor for night vision imaging[J]. ACS applied materials & interfaces, 2023, 15(33):39550-39558. |
| 备注/Memo: | 收稿日期：2025-04-14 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ 基金项目：浙江省自然科学基金（LQ21A040003） 第一作者：林 洁，硕士研究生，主要研究方向为无机发光材料。E-mail: liuhuihai@163.com *通信作者：张约品，教授，主要研究方向为无机发光材料。E-mail: zhangyuepin@nbu.edu.cn 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ |
