迁移型阻锈剂在既有混凝土结构中阻锈作用研究
PDF下载 (295)宋屹林,姚森元,舒海斌,柳俊哲.迁移型阻锈剂在既有混凝土结构中阻锈作用研究[J].宁波大学学报(理工版),2020,33(1):95-100.DOI:
SONG Yilin,YAO Senyuan,SHU Haibin,LIU Junzhe.Effect of migration-type rust inhibitor in existing structure concrete on rust prevention[J].Journal of Ningbo University(Natural Science & Engineering Edition),2020,33(1):95-100.DOI:
| Title: | Effect of migration-type rust inhibitor in existing structure concrete on rust prevention |
| 作者: | 宋屹林, 姚森元, 舒海斌, 柳俊哲 |
| Author(s): | SONG Yilin, YAO Senyuan, SHU Haibin, LIU Junzhe |
| 关键词: | 既有混凝土结构; 阻锈剂; 扩散; 修复措施 |
| Keywords: | existing concrete structure; corrosion inhibitor; diffusion; repairing measures |
| 分类号: | TU528.0 |
| 文献标识码: | A |
| 摘要: | 通过内掺氯盐混凝土试件和既有混凝土结构中迁移型阻锈剂的修复试验, 结合钢筋自然电位、腐蚀面积率和失重率, 综合评价迁移型阻锈剂修复措施的阻锈效果. 研究结果表明: 涂刷、灌注、复合修复均能起到良好的阻锈效果, 其中复合修复阻锈效果最佳; 涂刷、灌注修复时, 若达不到亚硝酸根离子与氯离子临界摩尔比, 会引起宏电池腐蚀, 加速钢筋锈蚀; 磷酸氢二钠阻锈性能弱于亚硝酸钠, 但不发生宏电池腐蚀. |
| Abstract: | By various repairing experiments of the migration type rust inhibitor in both chloride- containing concrete test blocks and the concrete in existing structures, the rust prevention effect of different repairing measures of the migration type rust inhibitor was determined by rebar natural potential, mass loss degree and corrosion area ration. The results showed that brushing repairing, perfusion repairing, and composite repairing can all achieve good rust-resisting effect, and composite repairing has the best effect on rust prevention; if brushing or perfusion repairing fails, it is unable to reach to the critical molar ratio of nitrite ion to chloride ion and it may cause the macro battery corrodes and accelerate the corrosion of steel bars; the rust resistance of disodium sulphate is weaker than that of sodium nitrite, but it does not cause macro battery corrosion to occur. |
| 参考文献 /References: | [1] 马世豪, 李伟华, 郑海兵, 等. 钢筋阻锈剂的阻锈机理及性能评价的研究进展[J]. 腐蚀与防护, 2017, 38(12):963-968. [2] Okeniyi J O, Omotosho O A, Ajayi O O, et al. Effect of potassium-chromate and sodium-nitrite on concrete steel-rebar degradation in sulphate and saline media[J]. Construction and Building Materials, 2014, 50:448-456. [3] Zhang Z W, Li Y S, Liu R. Failure behavior of adhesive bonded interface between steel and bamboo plywood[J]. Journal of Adhesion Science and Technology, 2016, 30(19):2081-2099. [4] Sánchez M, Alonso M C. Electrochemical chloride removal in reinforced concrete structures: Improvement of effectiveness by simultaneous migration of calcium nitrite[J]. Construction and Building Materials, 2011, 25(2):873-878. [5] 柳俊哲, 孙武, 贺智敏, 等. 亚硝酸盐在混凝土结构中的阻锈作用[J]. 硅酸盐学报, 2014, 42(5):607-612. [6] Zhang J L, Li Y S, Liu R, et al. Examining bonding stress and slippage at steel-bamboo interface[J]. Composite Structures, 2018, 194:584-597. [7] 戴燕华, 蒋义, 闫加利, 等. 基于亚硝酸盐的复合型阻锈剂性能研究[J]. 宁波大学学报(理工版), 2016, 29(4):96-100. [8] 曹忠露. 亚硝酸离子对钢筋腐蚀的抑制效应研究[D]. 扬州: 扬州大学, 2011. [9] Valcarce M B, Vázquez M. Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions[J]. Materials Chemistry and Physics, 2009, 115:313-321. [10] 唐聿明, 牛犇, 林冰, 等. NO2-及其浓度对混凝土模拟孔隙液中碳钢早期孔蚀的作用[J]. 腐蚀科学与防护技术, 2015, 27(2):123-128. [11] Mansour H, Dhouibi L, Idrissi H. Effect of phosphate-based inhibitor on prestressing tendons corrosion in simulated concrete pore solution contaminated by chloride ions[J]. Construction and Building Materials, 2018, 171(2):250-260. [12] Ngala V T, Page C L, Page M M. Corrosion inhibitor systems for remedial treatment of reinforced concrete. Part 2: Sodium monofluorophosphate[J]. Corrosion Science, 2003, 45(7):1523-1537. [13] JTJ270-1998. 水运工程混凝土试验规程[S]. [14] Assouli B, Ballivy G, Rivard P. Influence of environmental parameters on application of standard ASTM C876-91: Half cell potential measurements[J]. Corrosion Engineering, 2008, 43(1):93-96. [15] Zhang J L, Li Y S, Tong K T, et al. Deformation of steel-bamboo composite beam considering the effect of interfacial slippage[J]. Advanced Steel Construction, 2018, 14(3):324-336. [16] Pradelle S, Thiéry M, Baroghel-Bouny V. Sensitivity analysis of chloride ingress models: Case of concretes immersed in seawater[J]. Construction and Building Materials, 2017, 136:44-56. |
| 备注/Memo: | 收稿日期: 2018-09-20. 宁波大学学报(理工版)网址: http://journallg.nbu.edu.cn/ 基金项目: 国家自然科学基金(51778302); 宁波大学研究生科研创新基金(G15058). 第一作者: 宋屹林(1994-), 男, 浙江宁波人, 在读硕士研究生, 主要研究方向: 混凝土耐久性. E-mail: 969514704@qq.com *通信作者: 柳俊哲(1964-), 男, 黑龙江五常人, 教授, 主要研究方向: 混凝土耐久性. E-mail: junzheliu@163.com 宁波大学学报(理工版)网址:http://journallg.nbu.edu.cn/ |