基于MOFs/COFs的质量型气体传感器在二氧化碳检测中的应用
PDF下载 (440)张 彤,王旭坤.基于MOFs/COFs的质量型气体传感器在二氧化碳检测中的应用[J].宁波大学学报(理工版),2025,38(6):9-21.DOI:10.20098/j.cnki.1001-5132.2025.0418
ZHANG Tong,WANG Xukun.Metal organic and covalent organic framework-based mass-sensitive gas sensors for carbon dioxide detection application[J].Journal of Ningbo University(Natural Science & Engineering Edition),2025,38(6):9-21.DOI:10.20098/j.cnki.1001-5132.2025.0418
| Title: | Metal organic and covalent organic framework-based mass-sensitive gas sensors for carbon dioxide detection application |
| 作者: | 张 彤, 王旭坤 |
| Author(s): | ZHANG Tong, WANG Xukun |
| 关键词: | 金属有机框架/共价有机框架; 气体传感器; 石英晶体微天平; 质量敏感型; 二氧化碳 |
| Keywords: | metal-organic frameworks/covalent organic frameworks; gas sensor; quartz crystal microbalance; mass sensitivity; dioxidecarbon |
| 分类号: | TP212.2 |
| DOI: | 10.20098/j.cnki.1001-5132.2025.0418 |
| 文献标识码: | A |
| 摘要: | 二氧化碳（CO2）检测对监测气候变化和空气质量、管理工业过程以及保障人类健康不可或缺，但CO2的化学惰性和稳定性对实际检测提出了重大挑战。质量型气体传感器是一种高性能传感器，该传感器的特性量变化不依赖敏感材料的电学性质，只与敏感材料的吸附能力有关。金属有机框架（MOFs）孔隙率高且具有表面可调性，而共价有机框架（COFs）则以其优良的化学和热稳定性著称，在气体检测、重金属传感和薄膜测量等方面均有应用。为此，综述探讨了将MOFs和COFs整合到质量型气体传感器中以提升其性能。针对气体传感器的灵敏度、选择性、响应速度和稳定性（“4S”特性），提出了改进策略，可为未来基于MOFs/COFs的质量型CO2气体传感器的改进提供参考。 |
| Abstract: | Carbon dioxide (CO2) detection is indispensable for monitoring climate change, ensuring air quality, managing industrial processes, and safeguarding human health. Nevertheless, the chemical inertness and stability of CO2 pose significant challenges in advancing detection technologies in practical applications. The mass-sensitive gas sensor is a high-performance sensor device in which the change in the characteristic quantity of the sensor does not depend on the difference in the electrical amount of the sensitive material but is related only to the adsorption capacity of the exposed material. Metal-organic frameworks (MOFs), with their high porosity and surface tunability, and Covalent organic frameworks (COFs), known for their exceptional chemical and thermal stability, are examined for applications such as gas detection, heavy metal sensing, and thin film measurements. This review explores the integration of MOFs and COFs into mass-sensitive sensors to boost their performance, with improvement strategies proposed for gas sensors’ core “4S” characteristics, i.e., sensitivity, selectivity, response speed, and stability. It provides some ideas and suggestions for the future development of MOFs/COFs-based mass-sensitive carbon dioxide gas sensors. |
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| 备注/Memo: | 收稿日期：2025−04−25 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ 基金项目：国家自然科学基金（62371206）；国家重点研发计划（2021YFB3200402） 第一作者：张 彤，教授，主要研究方向为微纳传感材料与器件。E-mail: zhangtong@jlu.edu.cn 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ |
