氢气传感器最新研究进展与分析
PDF下载 (213)钟爱华,周涣欣,高 悦.氢气传感器最新研究进展与分析[J].宁波大学学报(理工版),2025,38(6):41-53.DOI:10.20098/j.cnki.1001-5132.2025.0521
ZHONG Aihua,ZHOU Huanxin,GAO Yue.Recent progress and analysis of hydrogen sensors[J].Journal of Ningbo University(Natural Science & Engineering Edition),2025,38(6):41-53.DOI:10.20098/j.cnki.1001-5132.2025.0521
| Title: | Recent progress and analysis of hydrogen sensors |
| 作者: | 钟爱华, 周涣欣, 高 悦 |
| Author(s): | ZHONG Aihua, ZHOU Huanxin, GAO Yue |
| 关键词: | 氢气传感器; 传感器种类; 氢气检测 |
| Keywords: | hydrogen sensor; types of sensors; hydrogen detection |
| 分类号: | TP212 |
| DOI: | 10.20098/j.cnki.1001-5132.2025.0521 |
| 文献标识码: | A |
| 摘要: | 氢能源作为清洁能源，在国家节能减排战略中具有重大意义，其清洁、高效的特性使其成为未来能源体系的核心支柱之一。然而，氢气“高度可燃、无色无味”的固有属性使其在实际应用中存在一定的安全隐患，因此氢气检测技术成为保障氢能安全、推动产业发展的关键支撑技术。针对近年来氢气传感器及其技术的发展情况，本文主要探讨了热导式、催化燃烧式、电化学式、光学式和功函数式氢气传感器的研究进展，同时对氢泄漏检测传感器技术的现状和发展进行了分析，并探讨了氢泄漏检测技术急需解决的问题和未来的发展方向。 |
| Abstract: | As a clean energy, hydrogen energy holds significant strategic importance under the national melody of energy conservation and emission reduction. Its clean and efficient characteristics establish its importance in the future energy system. However, the highly flammable, colorless, and odorless properties of hydrogen pose certain potential safety risks in practical applications. Therefore, hydrogen detection technology has become a key technology to ensure safety and promote the development of hydrogen energy industry. Aiming at the development of hydrogen sensors and their related technologies in recent years, this paper mainly discusses the research progress of thermal conductivity type, catalytic combustion type, electrochemical type, optical type, and work function type of hydrogen sensors. Meanwhile, it also introduces the status and development of hydrogen leakage detection technology, and explores the urgent problems to be solved and the future development direction of hydrogen detection technology. |
| 参考文献 /References: | [1] 王虹, 梁雪莲, 陈庆玺. 氢能产业政策研究[J]. 煤气与热力, 2020, 40(7):27-31. [2] BUTTNER W J, POST M B, BURGESS R, et al. An overview of hydrogen safety sensors and requirements[J]. International journal of hydrogen energy, 2011, 36(3):2462-2470. [3] 程一步. 2022年国内氢能产业发展动态及新政策对产业影响浅析[J]. 石油石化绿色低碳, 2022, 7(5):1-6. [4] 何青, 孟照鑫, 沈轶, 等. “双碳”目标下我国氢能政策分析与思考[J]. 热力发电, 2021, 50(11):27-36. [5] 杨曜光. 浅谈氢能及制氢的应用技术现状及发展趋势[J]. 新型工业化, 2020, 10(6):127-128. [6] 高慧, 杨艳, 赵旭, 等. 国内外氢能产业发展现状与思考[J]. 国际石油经济, 2019, 27(4):9-17. [7] 雷超, 李韬. 碳中和背景下氢能利用关键技术及发展现状[J]. 发电技术, 2021, 42(2):207-217. [8] WINTER C J. Hydrogen energy-abundant, efficient, clean: a debate over the energy-system-of-change[J]. International journal of hydrogen energy, 2009, 34(14):S1-S52. [9] 阳月, 杨明, 陆晖. 我国氢能产业发展综述[J]. 红水河, 2025, 44(1):54-57, 88. [10] 沈丹丹, 高顶云, 潘相敏. 氢能源利用安全性综述[J]. 上海节能, 2020(11):1236-1246. [11] CAO W G, LI W J, ZHANG L, et al. Flame characteristics of premixed H2-air mixtures explosion venting in a spherical container through a duct[J]. International journal of hydrogen energy, 2021, 46(52):26693-26707. [12] DWIVEDI S K, VISHWAKARMA M. Hydrogen embrittlement in different materials: a review[J]. International journal of hydrogen energy, 2018, 43(46): 21603-21616. [13] KOYAMA M, AKIYAMA E, LEE Y K, et al. Overview of hydrogen embrittlement in high-Mn steels[J]. International journal of hydrogen energy, 2017, 42(17):12706-12723. [14] SÁNCHEZ A L, WILLIAMS F A. Recent advances in understanding of flammability characteristics of hydrogen [J]. Progress in energy and combustion science, 2014, 41:1-55. [15] CAO W G, LI W J, YU S, et al. Explosion venting hazards of temperature effects and pressure characteris- tics for premixed hydrogen-air mixtures in a spherical container[J]. Fuel, 2021, 290:120034. [16] LHUILLIER C, BREQUIGNY P, CONTINO F, et al. Experimental study on ammonia/hydrogen/air combustion in spark ignition engine conditions[J]. Fuel, 2020, 269:117448. [17] HAN X L, WANG Z H, COSTA M, et al. Experimental and kinetic modeling study of laminar burning velocities of NH3/air, NH3/H2/air, NH3/CO/air and NH3/CH4/air premixed flames[J]. Combustion and flame, 2019, 206:214-226. [18] 郑津洋, 刘自亮, 花争立, 等. 氢安全研究现状及面临的挑战[J]. 安全与环境学报, 2020, 20(1):106-115. [19] 闫晓, 闫军芬, 陈珂, 等. 氢泄漏与扩散研究及加氢站安全防护[J]. 能源与节能, 2022(7):6-10, 40. [20] 张来斌, 胡瑾秋, 张曦月, 等. 氢能制-储-运安全与应急保障技术现状与发展趋势[J]. 石油科学通报, 2021, 6(2):167-180. [21] JIN Y, ZHENG Z, WEI D, et al. Detection of micro-scale Li dendrite via H2 gas capture for early safety warning[J]. Joule, 2020, 4(8):1714-1729. [22] BOON-BRETT L, BOUSEK J, BLACK G, et al. Identifying performance gaps in hydrogen safety sensor technology for automotive and stationary applications[J]. International journal of hydrogen energy, 2010, 35(1):373-384. [23] HÜBERT T, BOON-BRETT L, PALMISANO V, et al. Developments in gas sensor technology for hydrogen safety[J]. International journal of hydrogen energy, 2014, 39(35):20474-20483. [24] BERNDT D, MUGGLI J, WITTWER F, et al. MEMS- based thermal conductivity sensor for hydrogen gas detection in automotive applications[J]. Sensors and actuators A: physical, 2020, 305:111670. [25] WU Z P, ZHANG X D, CHEN L N, et al. Ultra-low-power, extremely stable, highly linear-response thermal conductivity sensor based on a suspended device with single bare Pt nanowire[J]. ACS sensors, 2024, 9(9):4721-4730. [26] HÜBERT T, BOON-BRETT L, BLACK G, et al. Hydrogen sensor: a review[J]. Sensors and actuators B: chemical, 2011, 157(2):329-352. [27] GORBOVA E, BALKOURANI G, MOLOCHAS C, et al. Brief review on high-temperature electrochemical hydrogen sensors[J]. Catalysts, 2022, 12(12):1647. [28] WANG C, YANG J X, LI J L, et al. Solid-state electrochemical hydrogen sensors: a review[J]. International journal of hydrogen energy, 2023, 48(80):31377-31391. [29] LEE E G, JUNG S W, JO Y E, et al. Electrochemical hydrogen sensor assembly for monitoring high- concentration hydrogen[J]. Physica status solidi, 2022, 219(20):2100782. [30] YI J X, ZHANG H, ZHANG Z B, et al. Hierarchical porous hollow SnO2 nanofiber sensing electrode for high performance potentiometric H2 sensor[J]. Sensors and actuators B: chemical, 2018, 268:456-464. [31] ZHANG W B, ZOU J, SUN J Y, et al. Fabrication and sensing performance of carrier-free catalytic combustion hydrogen sensors based on electrodeposition method[J]. International journal of hydrogen energy, 2024, 61:1356-1364. [32] PANAMA G, JO M, SHIM S S, et al. Hydrogen sensor with a thick catalyst layer anchored on soda-lime glass[J]. International journal of hydrogen energy, 2024, 55:875- 881. [33] DEL O H D, CHO I, YANG H, et al. Pt Nanostructures fabricated by local hydrothermal synthesis for low-power catalytic-combustion hydrogen sensors[J]. ACS applied nano materials, 2021, 4(1):7-12. [34] ZHANG X H, GUO L, WEI X R, et al. Thermo-optic nanomaterial fiber hydrogen sensor[J]. Nanomaterials, 2025, 15(6):440. [35] 张莉超, 黄嘉斌, 徐磊, 等. 基于镀钯微悬臂梁探针的光纤氢气传感器[J]. 激光与光电子学进展, 2023, 60(23):123-129. [36] XIONG C, ZHOU J T, LIAO C R, et al. Fiber-tip polymer microcantilever for fast and highly sensitive hydrogen measurement[J]. ACS applied materials & interfaces, 2020, 12(29):33163-33172. [37] DUAN P Y, DUAN Q L, PENG Q K, et al. Design of ultrasensitive gas sensor based on self-assembled Pd- SnO2/rGO porous ternary nanocomposites for ppb-level hydrogen[J]. Sensors and actuators B: chemical, 2022, 369:132280. [38] LU S H, ZHANG Y Z, LIU J Y, et al. Sensitive H2 gas sensors based on SnO2 nanowires[J]. Sensors and actuators B: chemical, 2021, 345:130334. [39] BADIE C, LEE J H, MIRZAEI A, et al. Enhanced sensitivity towards hydrogen by a TiN interlayer in Pd-decorated SnO2 nanowires[J]. Journal of materials chemistry A, 2023, 11(23):12202-12213. [40] LI Z X, XING X X, FENG D L, et al. Nitrogen-doped carbon microfibers decorated with palladium and palladium oxide nanoparticles for high-concentration hydrogen sensing[J]. Ceramics international, 2024, 50(12):21519-21525. [41] 涂建鑫, 邹杰, 孙靖远, 等. 基于钯纳米颗粒导电沟道的室温型氢气传感器的研究[J]. 传感技术学报, 2024, 37(1):16-21. [42] LI Z, FENG D, ZHANG Z, et al. Palladium hexagonal nanoparticles/carbon nanotubes/cellulose nanocrystals integrated over paper for wearable hydrogen sensing with fast response by bridging behavior[J]. Sensors and actuators B: chemical, 2025, 427:137153. [43] ZHANG M X, ZHAO C H, GONG H M, et al. Porous GaN submicron rods for gas sensor with high sensitivity and excellent stability at high temperature[J]. ACS applied materials & interfaces, 2019, 11(36):33124-33131. [44] ZHONG A H, SASAKI T, FAN P, et al. Integrated H2 nano-sensor array on GaN honeycomb nanonetwork fabricated by MEMS-based technology[J]. Sensors and actuators B: chemical, 2018, 255:2886-2893. [45] LUTHER B P, WOLTER S D, MOHNEY S E. High temperature Pt Schottky diode gas sensors on n-type GaN[J]. Sensors and actuators B: chemical, 1999, 56(1):164-168. [46] CHO M, YUN J, KWON D, et al. High-sensitivity and low-power flexible Schottky hydrogen sensor based on silicon nanomembrane[J]. ACS applied materials & interfaces, 2018, 10(15):12870-12877. [47] SHARMA N, PANDEY V, GUPTA A, et al. Recent progress on group Ⅲ nitride nanostructure-based gas sensors[J]. Journal of materials chemistry C, 2022, 10(34):11219-12157. [48] SHEN L, HEIKMAN S, MORAN B, et al. AlGaN/AlN/ GaN high-power microwave HEMT[J]. IEEE electron device letters, 2001, 22(10):457-459. [49] SCHALWIG J, MÜLLER G, EICKHOFF M, et al. Gas sensitive GaN/AlGaN-heterostructures[J]. Sensors and actuators B: chemical, 2002, 87(3):425-430. [50] BAIK K H, JUNG S, CHO C Y, et al. AlGaN/GaN heterostructure based Pt nanonetwork Schottky diode with water-blocking layer[J]. Sensors and actuators B: chemical, 2020, 317:128234. [51] SUN A F, YU H M, ZHOU Y, et al. Pd gated AlGaN/GaN high electron mobility transistor for ppb level hydrogen gas detection[J]. International journal of hydrogen energy, 2022, 47(39):17494-17503. [52] NGUYEN V C, CHA H, KIM H. High selectivity hydrogen gas sensor based on WO3/Pd-AlGaN/GaN HEMTs[J]. Sensors, 2023, 23(7):3465. [53] YU H M, SUN A F, LIU Y Q, et al. Capacitive sensor based on GaN honeycomb nanonetwork for ultrafast and low temperature hydrogen gas detection[J]. Sensors and actuators B: chemical, 2021, 346:130488. |
| 备注/Memo: | 收稿日期：2025−05−22 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ 基金项目：国家自然科学基金（62071307） 第一作者：钟爱华，博导/副教授，主要研究方向为气体传感芯片、传感器阵列和光电探测器。E-mail: zhongah@szu.edu.cn 宁波大学学报（理工版）网址：http://journallg.nbu.edu.cn/ |
