P.B.15:3数码印花用水性涂料墨水的制备与性能研究
PDF下载 (400)王 挺,王 丽,王 颖,张嘉楠.P.B.15:3数码印花用水性涂料墨水的制备与性能研究[J].宁波大学学报(理工版),2020,33(2):113-120.DOI:
WANG Ting,WANG Li,WANG Ying,ZHANG Jianan.Preparation and properties of P.B.15:3 water-based pigment ink for digital printing[J].Journal of Ningbo University(Natural Science & Engineering Edition),2020,33(2):113-120.DOI:
| Title: | Preparation and properties of P.B.15:3 water-based pigment ink for digital printing |
| 作者: | 王 挺, 王 丽, 王 颖, 张嘉楠 |
| Author(s): | WANG Ting, WANG Li, WANG Ying, ZHANG Jianan |
| 关键词: | 酞菁铜颜料; 稳定性; 数码印花; 水性涂料墨水 |
| Keywords: | copper phthalocyanine pigment; stability; digital printing; water-based pigment ink |
| 分类号: | TS194.2 |
| 文献标识码: | A |
| 摘要: | 采用单一变量法, 研究了PVP-8000、Solsperse-20000、BYK-190、Tween-20对酞菁铜Pigment Blue 15:3分散体系的离心稳定性、黏度、表面张力、颜料平均粒径的影响, 发现BYK-190相较于Solsperse-20000更适合在水中分散酞菁铜颜料. 通过正交实验筛选出各项性能较好的4种颜料分散体系, 并进行了流变性能的测试, 优化得到综合分散效果最佳的分散体系为: BYK- 190、PVP-8000和Tween-20的质量分数分别为3.5%、6.0%和5.0%, 比吸光度为0.943, 黏度为6.0m Pa·s, 表面张力为43.7 mN·m-1, 平均粒径为194.4 nm. |
| Abstract: | The effects of PVP-8000, Solsperse-20000, BYK-190, and Tween-20 on centrifugal stability, viscosity, surface tension and average particle size of Pigment Blue 15:3 dispersions are investigated by single factor experiment. The results suggest that BYK-190 is more suitable for dispersing the copper phthalocyanine pigment than Solsperse-20000 in water-based system. Four dispersions with good properties are selected by conducting the orthogonal experiment, in which their rheological properties are tested. In the optimized dispersion system, BYK-190, PVP-8000 and Tween-20 are found to have the mass fraction of 3.5%, 6.0% and 5.0%, respectively. The absorbance ratio is 0.943; the surface tension reads 43.7 mN·m-1; the viscosity reveals being 6.0 mPa·s; and the average particle size reaches 194.4nm. |
| 参考文献 /References: | [1] Guan Y, Tawiah B, Zhang L P, et al. Preparation of UV-cured pigment/latex dispersion for textile inkjet printing[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 462:90-98. [2] Fu S H, Fang K J, Zhang X, et al. Preparation of waterborne nanoscale pigment dispersions for formulation of ink jet inks[J]. Journal of Imaging Science and Technology, 2008, 52(5):050501-1-4. [3] Hakeim O A, Arafa A A, Zahran M K, et al. Characterisation and application of pigmented UV- curable inkjet inks[J]. Pigment & Resin Technology, 2018, 47(2):164-172. [4] Dong J N, Chen S, Corti D S, et al. Effect of Triton X-100 on the stability of aqueous dispersions of copper phthalocyanine pigment nanoparticles[J]. Journal of Colloid and Interface Science, 2011, 362(1):33-41. [5] 付少海, 关玉, 吴敏, 等. 纺织品喷墨印花墨水的研究进展[J]. 纺织导报, 2012(4):34-37. [6] Dong J N, Corti D S, Franses E I, et al. Adsorption of Myrj 45 on copper phthalocyanine pigment nanoparticles and effect on their dispersion stability in aqueous solution[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 390(1/2/3):74-85. [7] Zelina J P, Njue C K, Rusling J F, et al. Influence of surfactant-based microheterogeneous fluids on aggregation of copper phthalocyanine tetrasulfonate[J]. Journal of Porphyrins and Phthalocyanines, 1999, 3(3): 188-195. [8] 杨超, 王蕊, 蔡玉青, 等. Tween 20/Span 20和纤维素酶协同分散酞菁铜颜料[J]. 印染助剂, 2018, 35(4):35- 41. [9] 房宽峻, 王潮霞, 张霞. 一种纳米颜料喷墨打印墨水及其制备方法: CN1687258A[P]. 2005-10-26. [10] Sano T, Takemoto K, Watanabe K. Processes for producing pigment dispersion and ink composition: US20030374516[P]. 2004-11-16. [11] Agbo C, Jakpa W, Sarkodie B, et al. A review on the mechanism of pigment dispersion[J]. Journal of Dispersion Science and Technology, 2018, 39(6):874-889. [12] Zelina J P, Rusling J F. Molecular orientation in self-assembled films of copper phthalocyanine tetrasulfonate and a cationic surfactant[J]. Microporous Materials, 1995, 5(4):203-210. [13] 于辉, 王丽, 林施, 等. P.V.19数码印花用水性涂料墨水[J]. 印染, 2017, 43(21):30-35. [14] 郝龙云. 分散剂对超细有机颜料水性分散体系稳定性的影响[D]. 青岛: 青岛大学, 2003. [15] Zhou Y, Yu D, Wang C L, et al. Effect of ammonium salt of styrene-maleate copolymer on the rheology of quinacridone red pigment dispersion[J]. Journal of Dispersion Science and Technology, 2004, 25(2):209- 215. [16] 梅林. 水性聚合型分散剂对有机颜料分散性能的研究[D]. 上海: 复旦大学, 2010. [17] 徐燕莉. 非离子表面活性剂在颜料表面处理中的应用[J]. 北京化工大学学报(自然科学版), 1998, 25(3):77- 82. [18] 许增慧, 沈莉萍, 李翠萍, 等. 数码喷墨印花墨水的研究现状与发展趋势[J]. 印染助剂, 2013, 30(1):1-4. [19] 钱纪军, 陈爱平, 刘众鑫, 等. 炭黑中性笔墨水书写性能的流变学表征[J]. 精细化工, 2009, 26(5):506-508; 520. [20] Tadros T. Application of rheology for assessment and prediction of the long-term physical stability of emulsions[J]. Advances in Colloid and Interface Science, 2004, 108:227-258. [21] 李月月, 刘守军, 吴瑞娟, 等. 借助流变曲线优化中性墨水配方[J]. 精细化工, 2014, 31(9):1140-1144; 1172. [22] Haramagatti C R, Dhande P, Bhavsar R, et al. Role of surfactants on stability of iron oxide yellow pigment dispersions[J]. Progress in Organic Coatings, 2018, 120: 260-265. [23] Sis H, Birinci M. Wetting and rheological characteristics of hydrophobic organic pigments in water in the presence of non-ionic surfactants[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 455: 58-66. |
| 备注/Memo: | 收稿日期: 2019-10-22. 宁波大学学报(理工版)网址: http://journallg.nbu.edu.cn/ 基金项目: 宁波大学横向科技项目(HK2015000095). 宁波大学学报(理工版)网址:http://journallg.nbu.edu.cn/第一作者: 王挺(1994-), 女, 浙江台州人, 在读硕士研究生, 主要研究方向: 精细化学品. E-mail: 1013190334@qq.com *通信作者: 王丽(1963-), 女, 辽宁沈阳人, 教授, 主要研究方向: 精细化学品. E-mail: wangli1@nbu.edu.cn |